Producing lab-grown diamonds with chemical vapor deposition

Producing lab-grown diamonds with chemical vapor deposition

Diamonds are a highly demanded gem commonly used in both jewelry and a variety of industrial applications. For many years, large companies have been able to artificially inflate diamond prices by controlling the supply of mined diamonds. Recent improvements in lab-grow diamond production are disrupting the diamond industry.

Lab-grown diamonds are made using chemical vapor deposition

While lab-grow diamonds have been produced for some time in the Asia-Pacific region, they are now being manufactured across the world at a faster rate than ever before. This is leading to significant increases in diamond accessibility and decreases in cost.

HPHT and CVD techniques for diamond production

With consistent and quality-controlled manufacturing practices, lab-grown diamonds are identical to those formed naturally. Lab-grown diamonds are manufactured using one of two processes, high pressure and high temperature (HPHT) or chemical vapor deposition (CVD).

HPHT mimics the Earth’s natural process of creating diamonds, using extremely high heat and pressure conditions of about 2000°C and over 1.5 million PSI. Diamonds made using CVD are a newer development. This process imitates the formation of diamonds in interstellar gas clouds. The diamond is formed layer by layer as energy breaks the chemical bonds in gases.

Both HPHT and CVD can yield high-grade diamonds, but CVD has become the preferred approach for several reasons:

  • Most CVD processes operate at lower temperatures and pressures than HPHT processes, simplifying the manufacturing process.
  • CVD diamonds are chemically pure, whereas HPHT diamonds require the use of gases like nitrogen and boron that infiltrate the diamond.
  • CVD can be used for diamond deposition on substrates other than diamond.

This has resulted in technological advancements for many industries including optics, computer sciences, and tool production. The biggest challenge thus far to manufacturing diamonds via CVD is the inability to yield diamonds over 3.2 carats. This is mostly relevant in the jewelry industry.

Using CVD to form diamonds

CVD requires a process seed to act as the foundation for chemical deposition, such as a thin slice of diamond or a graphite source. The seed is placed into a chamber that is evacuated down to a high vacuum (about 20 millitorr) to prevent contamination. The chamber is then filled with a carbon-rich gas such as methane, and either hydrogen or oxygen.

Energy is used to break down the chemical bonds of the gases and build up the diamond layer by layer. This energy can be supplied using heat or ionized plasma.

Energy from heating

Gases are heated using either thermal or chemical activation. To thermally heat gases, a filament within the vacuum chamber is usually used to reach a target temperature to 2000-2500°C. A less common technique uses a torch to exothermically convert the process gases and heat the chamber to 500-1000°C.

Energy from ionized plasma

Ionized plasma is most commonly created using electrical or electromagnetic activation from microwaves or lasers. During ionization, diamond manufacturers must carefully regulate the temperature, pressure, and gas composition within the vacuum chambers. Changes or fluctuations in any of these three variables will impact the growth rate of the diamond, as well as its purity and color. The diagrams below demonstrate the balance of gas composition and the pressure/temperature ratio that is needed for diamonds to grow.

Triangle showing growth regions for synthetic diamonds based on the balance between carbon, hydrogen, and oxygen

Carbon/hydrogen/oxygen balance required for diamonds to grow

Triangle showing the impact of different hydrogen, carbon, and oxygen ratios on the necessary pressure and temperature conditions to make lab-grown diamonds using CVD

Impact of pressure and temperature on carbon solubility

Challenges of diamond manufacturing

Alicat IVC-series pressure controller with integrated vacuum sensor

IVC-Series pressure controller

Historically, downstream pressure control has been used in CVD processes. In a downstream system, a large throttle valve is used in combination with a separate control module to manage high volumetric flow rates.

There are many challenges manufacturers face when attempting to produce consistently high quality lab-grown diamonds. System stability, vacuum leaks, and component costs must each be carefully monitored.

Alicat devices used in diamond manufacturing

Our team of applications engineers has worked with diamond manufacturers to develop an upstream vacuum controller specifically designed to regulate pressure in CVD systems. These devices are advantageous for several reasons:

  • A fast-acting proportional valve enables faster system response and better stability
  • Wide operating range from 0.1% to 100% of full scale, with accuracy of ±0.5% of full scale
  • Flexible and accurate pressure control with an extremely fast, 2 ms sensor response time
  • Devices designed for use with vacuum systems undergo helium leak tests (to 1 × 109 atm-cc/sec)
  • The all-in-one instrument doesn’t need downstream throttle valves or separate control modules.

As the lab-grown diamond industry grows, Alicat is ready to help manufacturers develop the CVD systems necessary for diamond manufacturing. Vacuum pressure controllers ensure that pressures within the vacuum chambers are stable and accurate, maintaining the delicate balance of conditions required for diamonds to grow.